Real time X-ray imaging of solid state battery

July 01, 2019 //By Nick Flaherty
Researchers in the US have used an X-ray computed tomography (CT) scanner for real time imaging of a the operation of a solid state battery
Researchers in the US have used an X-ray computed tomography (CT) scanner for real time imaging of a solid state battery

The team at the Georgia Institute of Technology used the X-ray CT scanner to visualize in real time how cracks form near the edges of the interfaces of the materials in the solid state battery.

“Solid state batteries could be safer than lithium-ion batteries and potentially hold more energy, which would be ideal for electric vehicles and even electric aircraft,” said Matthew McDowell, an assistant professor in the George W. Woodruff School of Mechanical Engineering and the School of Materials Science and Engineering. “Technologically, it’s a very fast moving field, and there are a lot of companies interested in this.”

Solving the fracturing problem could be one of the first steps to unlocking the potential of solid state batteries, including their high energy density. The deterioration observed is likely to affect other types of solid state battery, the researchers noted, so the findings could lead to the design of more durable interfaces.

For the project, the research team built a solid-state battery in which a solid ceramic disc was sandwiched between two pieces of solid lithium. The ceramic disc replaced the typical liquid electrolyte. “Figuring out how to make these solid pieces fit together and behave well over long periods of time is the challenge,” said McDowell. “We’re working on how to engineer these interfaces between these solid pieces to make them last as long as possible.”

Working with an expert in X-ray imaging, Christopher Saldana, the researchers placed the solid state battery in the CT scanner and charged and discharged it, looking for physical changes indicative of degradation. Slowly over the course of several days, a web-like pattern of cracks formed throughout the disc. Those cracks are the problem and occur alongside the growth of an interphase layer between the lithium metal and solid electrolyte. The researchers found that this fracture during cycling causes resistance to the flow of ions.

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